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c/coa·submitted 5 months ago by u/anders_kuusela

area percent — 13 things I got wrong before I got it right

Labbranch of 13 comments

area percent — 13 things I got wrong before I got it right — a position I have arrived at slowly and would like tested. LC-MS gives you identity; UV purity gives you a relative quantity. A document with the first and not the second, or the reverse, is answering half the question. Asked BCH for the batch-specific…

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13 comments, started 5 months ago
u/coa_janitormod · c/coa422 points·5 months ago

ask for the storage condition the stability statement was written against

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u/anecdata_annie612 points·5 months ago

The PDF creation date being later than the analysis date is usually a re-issue or a re-export. It is worth one question and it is not evidence of anything on its own.

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u/nadia_kjaer475 points·5 months ago

Not quite. Two labs with different gradients can resolve a close-eluting impurity differently and both be reporting honestly.

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u/anders_kuuselaOP331 points·5 months ago

water content is on there and everyone skips it

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u/coa_janitorMOD263 points·5 months ago

Reminder: a question about a document is not an accusation about a supplier, and posts that blur the two get retitled.

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[deleted]101 points·5 months ago

[deleted]

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u/ismael_eriksen77 points·5 months ago

axis labels included, always

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u/amara_halonen45 points·5 months ago

HPLC-UV and LC-MS answer different questions

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u/halima_boateng199 points·5 months ago

Net peptide content is the fraction of the powder that is actually peptide once counterion, water and residual solvent are accounted for. A 99% pure acetate salt can still be about 85% peptide by mass.

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u/anders_kuuselaOP0 points·5 months ago

Small fix — 214nm, not 280nm. It matters here because the impurity you are asking about barely absorbs at the longer wavelength.

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u/reflux_report1 point·5 months ago

Are the related substances itemised or is it a single total?

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u/anders_kuusela1 point·5 months ago

Spent four months confusing area% and mass% in every post I made here. One explainer thread and it clicked permanently.

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u/tuva_aalto67 points·5 months ago

Agreed on asking for the storage condition. It is one line and it changes how you read the entire stability claim.

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How to read a certificate of analysis and what it does and does not tell you. Area% versus mass%, identity versus quantity, water content, related substances, acetate counterions, and the difference between a vendor-supplied COA and an independent test on the vial you actually received.

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